Ketene acetal metallocene complexes. Crystal structure of (C5H5) 2Ti(Cl)OC(OCH3)C(CH3)2

نویسندگان

  • Kai Hartmann
  • Josef Diebold
  • Hans-Herbert Brintzinger
چکیده

Titanocene and zirconocene ketene acetal derivatives have been prepared by reaction of the respective metallocene dichloride with the lithium enolate of isobutyric acid methyl ester. The crystal structure of (CsH s),Ti(CDOC(OCH 3):C(CH 3) is reported.

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Dipartimento di Chimica and Istituto CNR Meccanismi di Reazione c/o Dipartimento Roma “La Sapienza”, P.le A. Moro 5, 00185 uniroma1.it Institute for Complex Molecular Systems, E Box 513, 5600 MB Eindhoven, The Netherla † This work is dedicated to Professor Car ‡ Electronic supplementary information ( H, CH3 and OCH3), H NMR monitoring Cl, CH3 and OCH3) promoted by Et3 1HCF3CO2 . See DOI: 10.103...

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تاریخ انتشار 2001